Hydrodesulfurization (HDS), also called hydrotreatment or hydrotreating, is a catalytic chemical process widely used to remove sulfur (S) from natural gas and from refined petroleum products, such as gasoline or petrol, jet fuel, kerosene, diesel fuel, and fuel oils. The purpose of removing the sulfur, and creating products such as ultralowsulfur diesel, is to reduce the sulfur dioxide (SO 2 ...
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Flue gas desulphurisation (FGD) describes a process that removes sulphur dioxide (SO2) from a flue gas ( exhaust gas) stream. Sulphur dioxide is released to the atmosphere when fossil fuels are burnt and it is a leading contributor to acid rain. The FGD process has become critical to many industrial plants due to increasingly stringent ...
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The desulfurization process took place at a pH of 35, the coalparticle size was 7545 μm, the pulp density was 5%, the temperature was 35°C, and the incubation time was 8 h. Chemical studies also revealed a decrease in the ash content and an increase in the calorific value of coal from 6219 cal/g to 6406 and 6315 cal/g, which indicated ...
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The occurrence of sulfur in coal direct liquefaction residue affects its further high quality and high value utilization. Electrochemical desulfurization is characterized by mild reaction conditions, simple operation, easy separation of sulfur conversion products and little influence on the properties of the liquefied residue. An anodic electrolytic oxidation desulphurization experiment was ...
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Mechanism of Pyrite Microbial Desulfurization. The oxidation process of coal conversion is possible by microorganisms after getting influenced by the polyfunctional coal structure and this process usually depends on two main factors: size or shape of coal and surface properties of microorganisms (Konishi et al. 1990). The morphology and ...
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The most commonly required desulfurization process is in natural gas. Additional desulfurizing is required for flue gas, coal, and oil. Natural gas desulfurization is typically accomplished by adsorption. A bed of activated carbon is used as the filter for natural gas pipelines. As the natural gas runs through the pipeline, it runs through the ...
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Coal combustion is the largest single source of sulfur oxide pollution. Treatment of some major representative coals with aqueous ferric solution removes 40 to 75 percent of the sulfur content through near quantitative oxidation of the pyritic sulfur contained in the coal matrix. Elemental sulfur and iron sulfate are recovered as products ...
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Desulphurization is the removal of Sulphur Dioxide. The flue gas desulphurisation plants remove sulphur dioxides from the flue gas which is produced by boilers, furnaces, and other sources. Let us ...
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environment, the desulfurization and denitration of flue gas in the combustion process of coal has become an important step. This work summarizes the desulfurization and denitration ... In the wet desulfurization process, the scaling and blockage of equipment are easy to occur in the process site. In view of the above problems, a calciumsodium ...
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Oxidation is the most widely used process for coal desulfurization [17, 2932] due to its ability to . remove the p yritic sulfur [33] and the macromolecular network [34].
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This paper briefly introduces various methods of coal desulfurization (physical desulphurization, chemical desulfurization, biological desulfurization, etc.) and analyzes some problems existing in each method. The principle and research process of friction electrostatic separation technology and high gradient magnetic separation technology in precombustion desulfurization technology are ...
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A process flow diagram for the HDS plant is shown in Fig. 1. Desulfurization reactions take place in fixed bed catalytic reactors (∆ R) where a minimum ratio H 2 /hydrocarbon must be ensured for catalyst maintenance reasons. Reactors are fed with a blend of fuels of different qualities. The hydrocarbon (HC) feed is mixed with the recycled H 2 stream (R) and with makeup H 2 from the network.
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During the desulfurization process of coalfired power plants, there are many related parameters that affect the desulfurization efficiency. So it is very difficult to measure the desulfurization efficiency directly. In this paper, in order to reflect the relationship between monitoring process parameters and desulfurization efficiency better, a novel prediction model of desulfurization ...
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In this paper, a twostep desulfurization process for highsulfur coal was investigated. Two Chinese coals with the addition of 10 wt % potassium hydroxide or sodium hydroxide were pyrolyzed under an atmosphere of nitrogen or hydrogen in a fixedbed reactor at 600 °C, and then the obtained chars were washed with hot water. The results indicated that, without the addition of an alkali ...
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The method of zinc oxides can be used for fine desulfurization. With coal gases desulfurized by zinc oxides, the content of sulfur in coal gases could be as low as the level of 11000 parts per billion (ppb). ... Thus, if the desulfurization process could cut down the pressure and temperature losses of blast furnace gases, it would have ...
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In this work, the desulfurization process of highsulfur anthracite coal is discussed, and the desulfurization method of "reduced iron powder + heat treatment + magnetic separation" (named "RIHM") is designed. ... In this study, a highsulfur coal desulfurization experiment was carried out for highsulfur raw coal to reveal the internal ...
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sulfur than coal used in Japan and is hereafter referred to as "eastern bituminous highS coal"), and its excellent performance was confirmed by means of verification testing on equipment in the USA(4). In addition, to handle a wide variety of coals from around Fig. 2—Process Flow of New Fluegas Treatment System.
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Introduction. Flue gas desulfurized gypsum mainly comes from thermal power plants, smelters, and largeenterprise boilers, and contains industrial byproducts produced through a wet desulfurization combustion process, where SO 2 gas and lime slurry react under strong oxidation conditions. The main component of this gypsum is calcium sulfate dihydrate, which also contains calcium carbonate ...
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Coal combustion products (CCP) are fly ash, bottom ash (or boiler slag), and fluegas desulfurization gypsum. All have three fundamental properties: chemical composition, mineral composition, and particle size distribution. ... Coal combustion is a dirty process, releasing a range of pollutants including sulphur dioxide, nitrogen oxides, carbon ...
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The flue gas desulfurization (FGD) plant removes sulfur dioxides (SO 2) from flue gas produced by boilers, furnaces, and other sources. Mitsubishi Power effectively contributes to the prevention of air pollution through its wet limestonegypsum FGD process and seawater FGD process, and both processes can treat a large range of SO 2 ...
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Coalfired power plants can improve wet limestone scrubbing with advanced process control. ... The chemical reaction formula for this desulfurization process is: CaCO 3 + SO 2 + 2 H 2 O +½ O 2 ...
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Wet flue gas desulfurization technology has become the most widely used desulphurization technology. The researchers have applied analytic hierarchy process to analyze three aspects of desulfurization system in power plant including technology, economy and sustainable development [1]. Abboud et al. [2] gave the detailed economic evaluation on
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Flue gas desulfurization systems (FGD) or scrubbers are devices capable of sulfur removal efficiencies between 50% to 98%. Typically the highest removal is achieved by wet scrubbers and the lowest by dry scrubbers. They are used in coalandoil fired combustion units including utility and industrial boilers, municipal and medical waste ...
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The flue gas desulfurization process of coalfired power plant boiler mainly includes dry desulfurization, semidry desulfurization and wet desulfurization. The wet desulfurization process of limestone gypsum has mature technology and high desulfurization efficiency, and it is widely used. By
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In this study, coal fly ash was functionalized, using a simple onestep process (loading with Al3+ and sulfonation), to yield a solid acid catalyst (S/AlCFA) with strong acid sites. The catalyst was then used to produce furfural from xylose in a biphasic system (H2O(NaCl)/tetrahydrofuran). The furfural yield reached 82% at 180 °C60 min with catalyst/xylose ratio of : (w/w).
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Flue gas desulfurization (FGD) systems using lime or limestone as the chemical reagent are widely used throughout the world for SO 2 emissions control at coalfired power plants. Ammoniabased ...
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In 1978, Kirkbride proposed a desulfurization process: the raw coal will be properly pulverized, dried to remove free water, mixed with hydrogen and then treated by microwave radiation. H 2 reacts with S, N and O in coal producing H 2 S, NH 3 and water vapor thus achieving the purpose of desulfurization. The coal shall be as dry as possible ...
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Desulphurization of High Sulfur Coal by Mild Pyrolysis Combination with Magnetic Separation. Quanrun Liu H. Xia Guangxu Huang Chuanxiang Zhang M. Ma C. Wan. Materials Science, Chemistry. 2012. In this work, a new desulfurization process of high sulfur coal was designed and examined. The novel process involved pyrolysis of high sulfur coal at ...
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A material supplier from Belgium would like to produce limestone powder for his custome...
India is rich in various mineral resources and it is an important mineral processing market
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