In principle, the process of coal liquefaction involves chemical compounds which also occur in other carbochemical or petrochemical processes. It is well known that a number of these substances may be carcinogenic, teratogenic or mutagenic. The concentration of benzo(a)pyrene in coal liquefaction products can be between 50 and 60 μg g −1.
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Coal liquefaction is the "coal to liquids" process that takes two steps (coal gasification and gas to liquids) to "upgrade" coal to synthetic liquid fuels, such as synthetic diesel and synthetic gasoline. Coal liquefaction has been a proven technology used for over 100 years and is undergoing a renaissance by a number of companies that believe ...
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(A) Schematic representation of elution zones of different chemical families representative of a coalderived middle distillate; (B) SFCFID chromatogram of a coalderived middle distillate using the pyridine bonded phase showing the huge resolution of phenols from hydrocarbons.
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Coal liquefaction process employing fuel from a combined gasifier. Patent Schmid, B. Conversion of raw coal to distillate liquid and gaseous hydrocarbon products by solvent liquefaction in the presence of molecular hydrogen employing recycle of mineral residue is commonly performed at a higher thermal efficiency than conversion of coal to ...
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On the surface, it looks pretty much the same as the process of coal liquefaction. It is a thermochemical conversion process of organic material into liquid biocrude and coproducts. Depending on the process, it is usually conducted under moderate temperatures (300400°C, lower than coal liquefaction) and pressures (1020 MPa, similar or ...
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A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to ...
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The direct coal liquefaction process. usually produces a coal liquefaction residue (CLR) of about 30%. of its coal feed (Xu et al., 2014), and there is more than 80%. organic matter in the CLR ...
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The development of diagnostic instrumentation for monitoring coal liquefaction process streams is discussed. A sapphire optical fiber was used as an attenuated total reflectance (ATR) element in conjunction with Fourier transform infrared (FTIR) spectrometry to probe harsh liquefaction process streams. ATR provides a short, reproducible ...
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An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogenrich gases at ...
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Highlights. Coal liquefaction, the conversion of coal to a cleanburning, lowsulfurcontent fuel, is a technology that can augment petroleumderived products such as gasoline and boiler fuels and help meet the requirement for large supplies of liquid fuel. Direct liquefaction produces liquids through the interaction of coal and hydrogen at ...
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Indirect liquefaction of coal (ICL) has been found to be the most commercially viable process involving the gasification of coal. ICL includes two steps; in the first step, coal is converted into syngas ( Coal+H2OCO+H2), and during the last step, syngas is synthesized in the presence of a catalyst into liquid fuels.
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Pyrite addition to a coal liquefaction process (22, 26) is controlled (118) in inverse proportion to the calcium content of the feed coal to maximize the F. ( C.) liquid yield per unit weight of pyrite added (110). The pyrite addition is controlled in this manner so as to minimize the amount of pyrite used and ...
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In coal liquefaction process initial coal particle size can be considered as one of the important process parameters. In this work, particles of coal are prepared by pulverisation and separation ...
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When considering the development of coal liquefaction process using syngas, in addition to the above typical processes, hydrothermal liquefaction process is a technology worthy of reference. Hydrothermal liquefaction [110], [111], [112] is an effective and emerging technology that can convert both coals and biomass containing high moisture ...
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A process for liquefying a particulate coal feed to produce useful petroleumlike liquid products by steps which include: (a) contacting, in a liquefaction zone, said coal feed with a hydrogen donor solvent at temperature and pressure sufficient to hydroconvert and liquefy the coal, (b) separating the product from the liquefaction zone by distillation into fractions inclusive of a liquid ...
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This process is the only coal liquefaction scheme currently in use on a relatively large commercial scale; South Africa is currently using the Fischer−Tropsch process on a commercial scale in their complex. Thus, coal is converted to gaseous products at temperatures in excess of 800°C (1470°F), and at moderate pressures, to produce ...
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In materials science, liquefaction [1] is a process that generates a liquid from a solid or a gas [2] or that generates a nonliquid phase which behaves in accordance with fluid dynamics. [3] It occurs both naturally and artificially.
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Coal resources have been used to produce liquid transportation fuels by several process routes collectively referred to as coal liquefaction or, more generally stated, as coal to liquids (CTL). Early records of coal conversion to liquid fuel date to 1913 and an extraction process developed by Friedrich Bergius in Germany [ 7 ].
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All direct coal liquefaction methods, such as HCoal, SolventRefined Coal, and Exxon Donor Solvent processes, are alike in one principal point: coal is thermally solubilized with certain solvents, usually coalderived, with or without catalysts. If heated in a proper liquid for a short time, most of the coal dissolves.
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3. Features of NEDOL Process˜ The NEDOL Process is a coal liquefaction process developed exclusively in Japan. The process has integrated the advantages of three bituminous liquefaction processes (Direct Hydrogenation Process, Solvent Extraction Process, and Solvolysis Process), thus providing superiority in both technology and economics. The
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Abstract. The frontend design of a direct coal liquefaction process for the conversion of lignite into coal liquids by solvent extraction was investigated. The experimental work focused on ...
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Carlson, F B, Yardumian, L H, Atwood, M T. TOSCOAL process: coal liquefaction and char production. Paper No. 15e. [Application of oil shale retorting technology to coal processing; process description]. United States.
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Indirect liquefaction processes require first gasifying the solid feedstocks into a syngas. Therefore, while direct coal liquefaction (DCL) takes coal directly into a liquid phase, indirect coal liquefaction (ICL) consists of two major steps: (a) gasification to produce a synthesis gas (syngas); and (b) conversion of the carbon monoxide (CO) and hydrogen (H 2) in the syngas to a range of ...
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Indirect liquefaction process coal is liquefied through the FischerTropsch (FTS) process. ... Coal liquefaction is favoured by the simple skeletal structure that comprises mainly of simple aromatic rings which are less likely to be removed from the lignin basing on the building block for phenyl propane (Durie 1982).
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Coal Liquefaction It is an alternative route to produce diesel and gasoline and makes economic sense only in a world of high crude oil prices,Also called Coal to Liquid (CTL) technology. The process involves gasification of coal, which in turn will produce synthetic gas (a mix of CO+H2).
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History. In the past, coal was converted to make coal gas, which was piped to customers to burn for illumination, heating, and cooking. High prices of oil and natural gas led to increased interest in "BTU Conversion" technologies such as gasification, methanation and liquefaction. The Synthetic Fuels Corporation was a governmentfunded corporation established in 1980 to create a market ...
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New study shows liquefied natural gas might be worse for climate change than coal The findings have major implications for global climate goals and for the United States, which became the world ...
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A material supplier from Belgium would like to produce limestone powder for his custome...
India is rich in various mineral resources and it is an important mineral processing market
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